Someone with more knowhow in a context will be like a wizard.
How does it work?
They have loaded up their System 1 with more relevant experience.
But also they're able to "chunk" memories at a higher level.
Grandmasters of chess can look at any chess game and remember it in a second or two.
But if you show them a random board (i.e. not one generated by a legal game) they are no better than a novice at recalling the positions of pieces.
The grandmaster is chunking the knowledge of the board at a much higher layer of abstraction.
People who are able to work at higher layers of abstraction will be more effective with LLMs.